Journal
NEW JOURNAL OF CHEMISTRY
Volume 32, Issue 4, Pages 594-606Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b716292h
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The carbometalation reaction of zinc enolates and related stabilised organometallics on unactivated double bonds has emerged over the past decade as a mechanistically interesting and synthetically useful reaction. This Perspective is devoted to these challenging and apparently contra-thermodynamic transformations, with a special focus on recent mechanistic considerations involving radical-polar crossover reaction pathways.
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