A sensor based on blue luminescent graphene quantum dots for analysis of a common explosive substance and an industrial intermediate, 2,4,6-trinitrophenol

A rapid and effective sensor for the analysis of nitrophenol-based explosive substances, represented by trinitrophenol (TNP), has been developed with the use of the blue luminescent graphene quantum dots (GQDs); these GQDs are derived from citric acid by a pyrolysis procedure. They emit strong blue fluorescence at 450 nm after excitation at 365 nm, and TNP can quench this fluorescence because a fluorescence resonance energy transfer occurs. The quenching ratio (F-o -F)/F-o was related linearly to the concentration of TNP in the range of 0.1-15 mu mol L-1 with a detection limit of 0.091 mu mol L-1 (S/N = 3). The developed method exhibits high sensitivity, good linearity and reliable reproducibility for the quantitative analysis of TNP in water samples. The GQDs were used directly without any further treatment or complicated modification. (C) 2014 Elsevier B.V. All rights reserved.