Journal
SMALL
Volume 11, Issue 22, Pages 2593-2605Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201402799
Keywords
metal nanoframes; catalysis; plasmonics
Categories
Funding
- Collaborative Innovation Center of Suzhou Nano Science and Technology, MOST of China [2014CB932700, 2011CB921403]
- SRG-HSC
- NSFC [21203173, 51371164, 51132007, J1030412]
- Strategic Priority Research Program B of the CAS [XDB01020000]
- Fundamental Research Funds for the Central Universities [WK2340000050, WK2060190025]
- Whiting School of Engineering
- NSF
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Recently, metal nanoframes have received increased attention due to their unique spatial and physicochemical, e.g., catalytic and plasmonic properties. So far, a variety of synthetic procedures have been developed to fabricate metal nanoframes with different shapes, sizes and compositions. Typical synthesis of metal nanoframes involves two stages: 1) formation of solid nanocrystals and 2) hollowing out the interiors and side faces. In this review, solution-phase synthetic strategies are summarized, based on galvanic replacement reactions, oxidative etching, the Kirkendall effect, electrodeposition, and template-assisted growth, as well as one-pot synthesis. Their potential applications in catalysis and optical sensing are overviewed as well.
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