Journal
SMALL
Volume 11, Issue 39, Pages 5296-5304Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201501611
Keywords
C-60; catalyst; graphene oxide; graphene quantum dots; photoluminescence
Categories
Funding
- China Government 1000 plan Talent Program
- China MOE NCET program
- Natural Science Foundation of China [51322204]
- Fundamental Research Funds for the Central Universities [WK2060140014]
- NKBRPC [2011CB921400, 2012CB922001]
- NSFC [51172223, 21121003]
- Strategic Priority Research Program of CAS [XDB01020300]
- National Program for Support of Top-notch Young Professionals
- Institute of Basic Science, Korea
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The large-scale synthesis of graphene-oxide-like quantum dots (GOLQDs) is reported by oxidizing C-60 molecules using a modified Hummers method with a yield of approximate to 25 wt% readily achieved. The GOLQDs are highly soluble in water and in addition to hexagons have other carbon rings in the structure. They have an average height of approximate to 1.2 nm and a diameter distribution of 0.6-2.2 nm after drying on substrates. First-principle calculations indicate that a possible rupturing route may include the insertion of oxygen atoms to CC bonds in the C-60 molecule, followed by rupture of that CC bonds. The GOLQD suspension has a strong photoluminescence (PL) with peak position dependent on excitation wavelength. The PL is related to the size and emissive traps caused by oxygen-containing groups. The GOLQDs also catalyze the oxidation of benzyl alcohol with a high selectivity.
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