Journal
NATURE NANOTECHNOLOGY
Volume 6, Issue 11, Pages 740-746Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/NNANO.2011.165
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Funding
- Non-equilibrium Energy Research Center, Energy Frontier Research Center
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0000989]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1121262] Funding Source: National Science Foundation
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Switchable nanomaterials-materials that can change their properties and/or function in response to external stimuli-have potential applications in electronics, sensing and catalysis. Previous efforts to develop such materials have predominately used molecular switches that can modulate their properties by means of conformational changes. Here, we show that electrical conductance through films of gold nanoparticles coated with a monolayer of charged ligands can be controlled by dynamic, long-range gradients of both mobile counterions surrounding the nanoparticles and conduction electrons on the nanoparticle cores. The internal gradients and the electric fields they create are easily reconfigurable, and can be set up in such a way that electric currents through the nanoparticles can be modulated, blocked or even deflected so that they only pass through select regions of the material. The nanoion/counterion hybrids combine the properties of electronic conductors with those of ionic gels/polymers, are easy to process by solution-casting and, by controlling the internal gradients, can be reconfigured into different electronic elements (current rectifiers, switches and diodes).
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