4.8 Article

A multicaloric cooling cycle that exploits thermal hysteresis

Journal

NATURE MATERIALS
Volume 17, Issue 10, Pages 929-+

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/s41563-018-0166-6

Keywords

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Funding

  1. European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme-project Cool Innov [743116]
  2. DFG [SPP 1599]
  3. CICyT (Spain) [MAT2016-75823-R]
  4. HLD at HZDR, a member of the European Magnetic Field Laboratory

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The giant magnetocaloric effect, in which large thermal changes are induced in a material on the application of a magnetic field, can be used for refrigeration applications, such as the cooling of systems from a small to a relatively large scale. However, commercial uptake is limited. We propose an approach to magnetic cooling that rejects the conventional idea that the hysteresis inherent in magnetostructural phase-change materials must be minimized to maximize the reversible magnetocaloric effect. Instead, we introduce a second stimulus, uniaxial stress, so that we can exploit the hysteresis. This allows us to lock-in the ferromagnetic phase as the magnetizing field is removed, which drastically removes the volume of the magnetic field source and so reduces the amount of expensive Nd-Fe-B permanent magnets needed for a magnetic refrigerator. In addition, the mass ratio between the magnetocaloric material and the permanent magnet can be increased, which allows scaling of the cooling power of a device simply by increasing the refrigerant body. The technical feasibility of this hysteresis-positive approach is demonstrated using Ni-Mn-In Heusler alloys. Our study could lead to an enhanced usage of the giant magnetocaloric effect in commercial applications.

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