Journal
NATURE MATERIALS
Volume 10, Issue 12, Pages 947-951Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/NMAT3142
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Funding
- Yazaki Memorial Foundation for Science and Technology
- Japan Securities Scholarship Foundation
- CASIO Science Promotion Foundation
- Iwatani Naoji Foundation
- Canon Foundation
- Ministry of Education, Culture, Sports, Science and Technology, Japan [20110006]
- FIRST-JSPS
- CREST-JST
- Grants-in-Aid for Scientific Research [20110006, 23655041, 22350018, 21102004, 23350011, 23750039] Funding Source: KAKEN
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Secondary batteries using organic electrode-active materials promise to surpass present Li-ion batteries in terms of safety and resource price(1,2). The use of organic polymers for cathode-active materials has already achieved a high voltage and cycle performance comparable to those of Li-ion batteries(3-6). It is therefore timely to develop approaches for high-capacity organic materials-based battery applications. Here we demonstrate organic tailored batteries with high capacity by using organic molecules with degenerate molecular orbitals (MOs) as electrode-active materials. Trioxotriangulene (TOT), an organic open-shell molecule, with a singly occupied MO (SOMO) and two degenerate lowest-unoccupied MOs (LUMOs) was investigated. A tri-tert-butylated derivative ((t-Bu)(3)TOT) exhibited a high discharge capacity of more than 300 Ah kg(-1), exceeding those delivered by Li-ion batteries. A tribrominated derivative (Br3TOT) was also shown to increase the output voltage and cycle performance up to 85% after 100 cycles of the charge-discharge processes.
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