4.8 Article

Controlled drop emission by wetting properties in driven liquid filaments

Journal

NATURE MATERIALS
Volume 10, Issue 5, Pages 367-371

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/NMAT2998

Keywords

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Funding

  1. Direccion General de Investigacion (Spain) [FIS 2009-12964-C05-02, FIS 2008-04386]
  2. DURSI [SGR2009-00014, SGR2009-634]
  3. Conacyt (Mexico)
  4. Fundacion Carolina (Spain)
  5. EPSRC [EP/D050952/1]
  6. EPSRC [EP/D050952/1] Funding Source: UKRI
  7. Engineering and Physical Sciences Research Council [EP/D050952/1] Funding Source: researchfish

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The controlled formation of micrometre-sized drops is of great importance to many technological applications(1-5). Here we present a wetting-based destabilization mechanism of forced microfilaments on either hydrophilic or hydrophobic stripes that leads to the periodic emission of droplets. The drop emission mechanism is triggered above the maximum critical forcing at which wetting, capillarity, viscous friction and gravity can balance to sustain a stable driven contact line. The corresponding critical filament velocity is predicted as a function of the static wetting angle, which can be tuned through the substrate behaviour, and shows a strong dependence on the filament size. This sensitivity explains the qualitative difference in the critical velocity between hydrophilic and hydrophobic stripes, and accounts for previous experimental results of splashing solids(6). We demonstrate that this mechanism can be used to control independently the drop size and emission period, opening the possibility of highly monodisperse and flexible drop production techniques in open microfluidic geometries.

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