Journal
NATURE CHEMICAL BIOLOGY
Volume 8, Issue 5, Pages 428-430Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/NCHEMBIO.901
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Funding
- Fonds der Chemischen Industrie
- European Research Council (ERC) under the European Union
- ERC [268309]
- European Research Council (ERC) [268309] Funding Source: European Research Council (ERC)
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We developed an enantioselectively catalyzed tandem synthesis of structurally and stereochemically complex molecules that forms four carbon-carbon bonds and sets eight stereocenters with high regio-, diastereo- and enantioselectivity. It can be programmed to yield different stereoisomers by varying only the order of combination of a common set of reagents and catalysts. We report what is to our knowledge the first synthesis of both enantiomers of a chiral compound using the same chiral catalyst.
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