Journal
NATURAL PRODUCT RESEARCH
Volume 29, Issue 2, Pages 141-148Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/14786419.2014.968150
Keywords
(-)-cytisine; high pressure; aza-Michael reaction
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Funding
- Russian Foundation for Basic Research [12-03-00724-a]
- Foundation of Bashkortostan Republic for Young Scientists
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The first example of aza-Michael reaction of 12-N-carboxamide of quinolizidine alkaloid (-)-cytisine with alpha,beta-unsaturated ketones, dimethyl acetylenedicarboxylate and beta-nitrostyrene under high pressure condition has been described. It has been shown that the [4+2]-cycloaddition takes place in the case with N-phenylmaleimide.
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