4.6 Article

Controlled synthesis of transition metal/conducting polymer nanocomposites

Journal

NANOTECHNOLOGY
Volume 23, Issue 33, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/23/33/335603

Keywords

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Funding

  1. Department of Commerce, National Science Foundation Award [CMMI-1000491]
  2. Auburn University
  3. World-Class University Program (MEST through NRF) [R31-10026]

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A novel displacement reaction has been observed to occur between conducting polymers (CP) and metal salts which can be used to fabricate nanostructured CP-metal composites in a one-pot manner. Vanadium pentoxide (V2O5) nanofiber is used during the synthesis as the reactive seeds to induce the nanofibril CP-metal network formation. The CP-metal nanocomposites exhibit excellent sensory properties for hydrogen peroxide (H2O2) detection, where both high sensitivity and a low detection limit can be obtained. The sensory performance of the CP-metal composite can be further enhanced by a facile microwave treatment. It is believed that the CP-metal nanofibril network can be converted to a carbon-metal network by a microwave-induced carbonization process and result in the sensory enhancement.

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