Journal
NANOTECHNOLOGY
Volume 19, Issue 49, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0957-4484/19/49/495707
Keywords
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Funding
- Korea Science and Engineering Foundation (KOSEF) by the Korea government (MOST) [R01-2007-000-20385-0]
- SRC/ERC program of MOST/KOSEF [R11-2005-065]
- National Research Foundation of Korea [R11-2005-065-05001-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Hyperbranched polyurethane (HBPU) nanocomposites with multi-walled carbon nanotubes (MWNTs) were prepared by in situ polymerization on the basis of poly(epsilon-caprolactone) diol as the soft segment, 4,4'-methylene bis(phenylisocyanate) as the hard segment, and castor oil as the multifunctional group for the hyperbranched structure. A dominant improvement in the dispersion of MWNTs in the HBPU matrix was found, and good solubility of HBPU-MWNT nanocomposites in organic solvents was shown. Due to the well-dispersed MWNTs, the nanocomposites resulted in achieving excellent shape memory properties as well as enhanced mechanical properties compared to pure HBPU.
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