Journal
NANOSCALE AND MICROSCALE THERMOPHYSICAL ENGINEERING
Volume 17, Issue 2, Pages 112-123Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/15567265.2012.761305
Keywords
microcapsules; thermal properties; thermal energy storage material
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Funding
- National Natural Science Foundation of China [50776043]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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This article presents the preparation and characterization of microencapsulated paraffin microcapsules with silicon dioxide (SiO2) shells as thermal energy storage materials. The microcapsules were prepared using a sol-gel method. Paraffin was used as the core material, and SiO2 prepared with methyl triethoxysilane (MTES) acted as the shell material. The morphology and particle size of the microcapsules were investigated using scanning electron microscopy (SEM). The chemical characterization of the microcapsules was measured using Fourier transform infrared spectroscope (FTIR). The crystalloid phase of the microcapsules was measured using X-ray diffraction (XRD). The thermal properties and thermal stability of the microcapsules were analyzed using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The FTIR, XRD, and SEM results showed that the paraffin was encapsulated in the shell of the SiO2. The DSC results indicated that the typical microcapsules melted at 57.96 degrees C with a latent heat of 156.86 kJ/kg and solidified at 55.78 degrees C with a latent heat of 144.09 kJ/kg at microencapsulation ratio of 82.2%. The TGA and DTG results showed that the microcapsules had good thermal stability. The SiO2 shells improved the thermal stability of the microcapsules.
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