4.8 Article

Synthesis of a 3D network of Pt nanowires by atomic layer deposition on a carbonaceous template

Journal

NANOSCALE
Volume 6, Issue 12, Pages 6939-6944

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr00982g

Keywords

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Funding

  1. Research Foundation - Flanders (FWO)
  2. European Research Council under the European Union [239865-COCOON, 246791-COUNTATOMS, 335078-COLOURATOM]
  3. IWT-SBO SOSLion
  4. Belgian government through Interuniversity Attraction Poles (IAP-PAI)
  5. [UGENT-GOA-01G01513]

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The formation of a 3D network composed of free standing and interconnected Pt nanowires is achieved by a two-step method, consisting of conformal deposition of Pt by atomic layer deposition (ALD) on a forest of carbon nanotubes and subsequent removal of the carbonaceous template. Detailed characterization of this novel 3D nanostructure was carried out by transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS). The characterization showed that this pure 3D nanostructure of platinum is self-supported and offers an enhancement of the electrochemically active surface area by a factor of 50.

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