Journal
NANOSCALE
Volume 6, Issue 4, Pages 2131-2136Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr05228a
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Funding
- Institute for Basic Science (IBS) in Korea
- Global Frontier R&D Program on Center for Multiscale Energy System
- National Research Foundation (NRF) [2012M3A6A7054283]
- Basic Science Research Program through the NRF under the Ministry of Science, ICT & Future (MSIF), Korea [NRF-2012R1A6A3A04040490]
- Center for Integrated Smart Sensors
- MSIF as Global Frontier Project [CISS-2012M3A6A6054186]
- National Research Council of Science & Technology (NST), Republic of Korea [2V03250] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2012M3A6A6054193, 2011-0031571, 21A20130000016] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Edge-exposed MoS2 nano-assembled structures are designed for high hydrogen evolution reaction activity and long term stability. The number of sulfur edge sites of nano-assembled spheres and sheets is confirmed by Raman spectroscopy and EXAFS analysis. By controlling the MoS2 morphology with the formation of nano-assembled spheres with the assembly of small-size fragments of MoS2, the resulting assembled spheres have high electrocatalytic HER activity and high thermodynamic stability.
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