Journal
NANOSCALE
Volume 6, Issue 18, Pages 10569-10573Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr03075c
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Funding
- Welch Foundation [F-816]
- National Natural Science Foundation of China [51025207]
- 973 Program of China [2012CB821701]
- NSFC [21121061]
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Two series of Cd-Ln clusters: nano-drum [Ln(8)Cd(24)L(12)(OAc)(48)] and nano-double-drum [Ln(12)Cd(44)L(20)Cl(30)(OAc)(54)] (Ln = Nd and Yb) were prepared using a flexible Schiff base ligand bearing two aryl-Br groups. Chloride (Cl-) ions, together with the interactions of Br with other electronegative atoms, play a key role in the formation of the nano-double-drums. The structures were studied by TEMand photophysical properties were determined.
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