4.8 Article

Facile and cost effective synthesis of mesoporous spinel NiCo2O4 as an anode for high lithium storage capacity

Journal

NANOSCALE
Volume 6, Issue 17, Pages 10071-10076

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr02183e

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Funding

  1. National Research Foundation of Korea (NRF) [2012R1A2005977]
  2. Ministry of Science, ICT & Future Planning (MSIP), Korea, under the Convergence Information Technology Research Center (C-ITRC) support program [NIPA-2013-H0301-13-1009]

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To fulfill the high power and high energy density demands for Li-ion batteries (LIBs) new anode materials need to be explored to replace conventional graphite. Herein, we report the urea assisted facile co-precipitation synthesis of spinel NiCo2O4 and its application as an anode material for LIBs. The synthesized NiCo2O4 exhibited an urchin-like microstructure and polycrystalline and mesoporous nature. In addition, the mesoporous NiCo2O4 electrode exhibited an initial discharge capacity of 1095 mA h g(-1) and maintained a reversible capacity of 1000 mA h g(-1) for 400 cycles at 0.5 degrees C-rate. The reversible capacity of NiCo2O4 could still be maintained at 718 mA h g(-1), even at 10 degrees C. The mesoporous NiCo2O4 exhibits great potential as an anode material for LIBs with the advantages of unique performance and facile preparation.

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