Journal
NANOSCALE
Volume 6, Issue 19, Pages 11024-11030Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr03850a
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Funding
- European Union [267143]
- Marie Curie Intra European Fellowship within 7th European Community Framework Programme [327706]
- European Union [267143]
- Marie Curie Intra European Fellowship within 7th European Community Framework Programme [327706]
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The electron transfer kinetics associated with both the reduction of oxygen and of protons to form hydrogen at gold nanoparticles are shown to display strong retardation when studied at citrate capped ultra small (2 nm) gold nanoparticles. Negative nanocatalysis in the hydrogen evolution reaction (HER) is reported for the first time.
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