Journal
NANOSCALE
Volume 6, Issue 16, Pages 9806-9816Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nr00791c
Keywords
-
Categories
Funding
- CNRS
- ANR [SIDERUS BLAN-08-0010-03]
- ANR-DFG (MOCA-NANO) [ANR-11-INTB-1011, DFG-911/19-1]
- Interreg Sudoe (TRAIN2 project)
- European Union for ERC Advanced Grant [NANOSONWINGS 2009-246763]
- CNRS-MPG cooperation
- HPCs CALcul en MIdi-Pyrenees (CALMIP-Hyperion) [P0611]
- Grand Equipement National de Calcul Intensif (GENCI-TGCC-Curie) [6211]
- Agence Nationale de la Recherche (ANR) [ANR-11-INTB-1011] Funding Source: Agence Nationale de la Recherche (ANR)
Ask authors/readers for more resources
Two series of ruthenium nanoparticles stabilized either by a polymer (polyvinylpyrrolidone; Ru/PVP) or a ligand (bisdiphenylphosphinobutane; Ru/dppb) were reacted with tributyltin hydride [(n-C4H9)(3)SnH] leading to tin-decorated ruthenium nanoparticles, Ru/PVP/Sn and Ru/dppb/Sn. The Sn/Ru molar ratio was varied in order to study the influence of the surface tin content on the properties of these new nanoparticles, by comparison with Ru/PVP and Ru/dppb. Besides HRTEM and WAXS analyses, spectroscopic techniques (IR, NMR and Mossbauer) combined with theoretical calculations and a simple catalytic test (styrene hydrogenation) allowed us to evidence the formation of mu(3)-bridging SnR groups on the ruthenium surface as well as to rationalize their influence on surface chemistry and catalytic activity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
