Journal
NANOSCALE
Volume 5, Issue 2, Pages 508-512Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nr32948d
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Funding
- Collaborative Research Program of the Institute for Chemical Research, Kyoto University
- [21685003]
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The effect of Pd doping on the ligand-exchange reactivity of Au-25(SC12H25)(18) was studied by comparing the ligand-exchange reactivity of [Au-25(SC12H25)(18)](-) and [PdAu24(SC12H25)(18)](0) and the results clearly demonstrate that, regardless of the kind of incoming thiols and solvents, Pd doping greatly increases the rate of ligand exchange of Au-25(SC12H25)(18), indicating an enhanced ease of ligand exchange.
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