Journal
NANOSCALE
Volume 5, Issue 4, Pages 1301-1304Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nr32518g
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Funding
- Penn State MRSEC [NSF-DMR-0820404]
- Air Force Office of Scientific Research [FA9550-10-1-0509]
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We have observed by NMR spectroscopy that the diffusive movement of a ruthenium-based Grubbs' catalyst increases during ring-closing metathesis as a function of the substrate concentration. This is one of the smallest single molecule motors to exhibit catalytically driven motion.
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