Journal
NANOSCALE
Volume 5, Issue 24, Pages 12136-12139Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr04332k
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Funding
- Deutsche Forschungsgemeinschaft [DFG-SFB 953]
- European Research Council (ERC) [246622 - GRAPHENOCHEM]
- Cluster of Excellence 'Engineering of Advanced Materials (EAM)'
- U.S. National Science Foundation (NSF) [CHE 957793, CHE 1310363]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1310363] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0957793] Funding Source: National Science Foundation
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We present the first example of azide functionalization on the surface of graphene oxide (GO), which preserves thermally unstable groups in GO through the mild reaction with sodium azide in solids. Experimental evidence, by N-15 solid-state NMR and other spectroscopic methods, indicates the substitution of organosulfate with azide anions as the reaction mechanism.
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