Journal
NANOSCALE
Volume 5, Issue 24, Pages 12565-12573Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3nr02359a
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Funding
- Spanish MINECO [MAT2012-38318-C03]
- MOLCHIP from Gobierno de Aragon
- MICINN
- Red de Bibliotecas del CSIC
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Direct measurements of the linear ac susceptibility and magnetic relaxation of a few Mn-12 monolayers deposited on a mu-SQUID sensor are reported. In order to integrate the molecules into the device, DPN has been the technique of choice. It enabled the structuration of the molecules on the most sensitive areas of the sensor without the need for any previous functionalization of the molecule or the substrate, while controlling the number of molecular units deposited on each array. The measurements reveal that their characteristic SMM behaviour is lost, a fact that is attributed to molecular distortions originated by the strong surface tensions arising at the molecular interphases.
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