Journal
NANOSCALE
Volume 4, Issue 21, Pages 6714-6717Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nr32171h
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Funding
- Air Force Office of Scientific Research [FA9550-11-1-9999, FA9550-11-1-0147]
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Thiolate-protected gold nanoclusters are explored for catalytic application in the selective oxidation of sulfide to sulfoxide by PhIO. The TiO2-supported Au-25(SR)(18) nanocluster catalysts give rise to high catalytic activity (e.g. similar to 97% cony. of Ph-S-CH3 and similar to 92% selectivity for Ph-S(=O)-CH3 sulfoxide) and show excellent recyclability in the sulfoxidation process.
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