Journal
NANOSCALE
Volume 4, Issue 14, Pages 4095-4098Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nr30444a
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Funding
- Academy of Finland (FiDiPro project)
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A simple one-pot method for the preparation of subnanometre-size benzotriazolate (BTA) protected copper clusters, Cu(n)BTA(m), is reported. The clusters were analyzed by optical and infrared spectroscopy, mass spectrometry and transmission electron microscopy together with computational methods. We suggest a structural motif where the copper core of the Cu(n)BTA(m) clusters is protected by BTA-Cu(I)-BTA units.
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