Journal
NANOSCALE
Volume 4, Issue 21, Pages 6876-6879Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nr32193a
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Funding
- NNSF of China [21171013]
- Ministry of Science and Technology of China [2013CB933402]
- NSF of Jiangsu province of China [BK2012611]
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A new metallofullerene Sm@C-2v(3)-C-80 was synthesized and characterized. X-Ray analysis showed that the endohedral Sm atom undergoes a hopping motion between several off-center sites, even at low temperature. In addition, a comparative electrochemical study between Sm@C-2v(3)-C-80 and Yb@C-2v(3)-C-80 revealed their different redox potentials, suggesting a metal-induced effect on their redox profiles.
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