4.8 Article

A facile approach toward transition metal oxide hierarchical structures and their lithium storage properties

Journal

NANOSCALE
Volume 4, Issue 12, Pages 3718-3724

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2nr30525a

Keywords

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Funding

  1. AcRF of MOE (Singapore) [Tier 1 RG 31/08, NRF2009EWT-CERP001-026]
  2. Singapore Ministry of Education [MOE2010-T2-1-017]
  3. A*STAR SERC [1021700144, Singapore MPA 23/04.15.03 RDP 009/10/102, MPA 23/04.15.03 RDP 020/10/113]

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A simple, non-template, non-surfactant and environmentally friendly hydrothermal method is presented based on the controlled release of the reactants into the reaction solvents to induce slow nucleation and growth of three-dimensional hierarchical nanostructures of transition metal oxides. This method is a general approach, which can be used to prepare Co3O4, CuO, and Ni(OH)(2)/NiO. These metal oxides with hierarchical nanostructures can be used as anode materials for lithium-ion batteries with good Li storage performance, e. g. high specific capacities and stable cyclability.

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