4.8 Article

A novel lift-off method for fabricating patterned and vertically-aligned W18O49 nanowire arrays with good field emission performance

Journal

NANOSCALE
Volume 3, Issue 4, Pages 1850-1854

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nr01007c

Keywords

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Funding

  1. Science and Technology Ministry of China [2010CB327703, 2007CB935501, 2008AA03A314]
  2. National Natural Science Foundation of China [U0634002, U0734003, 50802117, 51072237, 50725206]
  3. Education Ministry of China [20070558063, 2009-30000-3161452]
  4. Science and Technology Department of Guangdong Province
  5. Economic and Information Industry Commission of Guangdong Province
  6. Science and Technology Department of Guangzhou City

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A novel lift-off method has been developed for fabricating patterned W18O49 nanowires in vertical arrays and on a large scale. These W18O49 nanowire arrays have an average diameter of about 30 nm, and their lengths range from 2-3 mm. In every pattern of a 2 inch sample, the nanowires exhibit the same morphology and growth density. They are single crystals with monoclinic structure and grow along the [010] direction. Field emission (FE) measurements show that they have a turn-on field of 6.2 V mu m(-1) and their emission current density can reach 500 mu A cm(-2) at an electric field of 10.9 V mu m(-1). Because the W18O49 nanowire patterns synthesized by this simple method still have good FE performance, comparable to many cathode nanostructures with excellent FE properties, it suggests that it may provide an effective and simple preparation technique for patterned growth of nanowire arrays in future FE applications.

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