Journal
NANOSCALE
Volume 3, Issue 6, Pages 2421-2429Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nr00968g
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Funding
- Next Generation Super Computing Project (Nanoscience Project)
- Nanotechnology Support Project
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- JST
- MICINN
- Sumitomo Foundation
- [20108001]
- [20245006]
- [20036008]
- [20038007]
- Grants-in-Aid for Scientific Research [22750030, 20108001] Funding Source: KAKEN
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Since the first discovery of fullerenes in 1985, the insertion of one or more atoms into a hollow fullerene cage has been attempted. Furthermore, synthesis and extraction of metallofullerene, La@C-n, were reported in 1991. Recent successful isolation and purification of metallofullerenes have facilitated the investigation of their chemical properties. This mini-review presents a summary of the recent progress of chemical functionalization and supramolecular chemistry of M@C-82. Selective functionalization and successful structural analysis of derivatives have revealed their chemical features arising from endohedral metal doping.
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