Journal
NANOSCALE
Volume 2, Issue 12, Pages 2601-2606Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nr00574f
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Funding
- ANR [ANR-07-CP2D-02-03]
- Ministere de l'enseignement superieur et de la recherche
- CNPq
- CAPES
- INCT-Catal
- Alexander-von-Humboldt Foundation
- Erasmus programme
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The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.
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