Journal
NANOSCALE
Volume 2, Issue 12, Pages 2652-2656Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0nr00466a
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Funding
- NSFC [20721061, 50725311, 60801037]
- Ministry of Science and Technology of China [2006CB806200, 2006CB932100, 2009CB930400]
- Chinese Academy of Sciences
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Anthracene and its derivatives are used to demonstrate a simple way to cast assemble nanowires of organic semiconductors with tuning of intermolecular non-covalent interactions by molecular design. The tuning of intermolecular interactions could be achieved by (i) decreasing intermolecular hydrophobic interactions by linking hydrophilic side chains to anthracene rings, (ii) increasing intermolecular interaction for self-assembly with the assistance of hydrogen bonds, and (iii) enhancing molecular pi-pi interaction by increasing the conjugated dimension of the compounds.
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