Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 209, Issue -, Pages 359-367Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2014.11.144
Keywords
Fluorescence chemosensor; Aluminium; Fluoride; Cyanide; Crystal structure; Bioimaging
Funding
- National Natural Science Foundation of China [20971015, 21073013]
- Fundamental Research Funds for the Central Universities
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A chemosensor 3-[(2-hydroxybenzylidene)-amino]-1H-pyridin-2-one (HL) for multi-ions was synthesized and characterized by single-crystal X-ray diffraction. HL is a turn-on fluorescence chemosensor for Al3+, F-, and CN- ions in DMSO. F- and CN- anions could be further distinguished by the ratiometric absorption spectrometry method. Job plot and H-1 NMR data showed that the binding stoichiometries of HL with Al3+, F-, or CN- all were 1 :1. Further observations of H-1 NMR titration and ESI-MS showed that the possible fluorescent species of Al3+ with HL was [AlL(OH)(DMSO)(2)](+) in DMSO. The spectroscopic observations of the Al(III) complex showed that the two oxygen atoms and one imine nitrogen atom of HL were coordinated to the Al(III) ion. While the crystal structure of the Ni(II)-L complex confirmed the tridentate coordination mode of HL in the complexes. The experimental results revealed that HL and F- ion formed hydrogen bond in DMSO, while CN- attacked the carbon atom at -C=N of HL to undergo a nucleophilic addition. The theoretical calculations confirmed that HL showed very weak fluorescence because of the excited-state intramolecular proton transfer (ESIPT). The turn-on sensing of HL to Al3+, F-, and CN- ions arose from the inhibition of ESIPT. MU tests showed that HL was low toxic to cells. Also, HL could probe intracellular Al3+ and F- ions by bioimaging. (C) 2014 Elsevier B.V. All rights reserved.
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