4.8 Article

High thermal conductivity of suspended few-layer hexagonal boron nitride sheets

Journal

NANO RESEARCH
Volume 7, Issue 8, Pages 1232-1240

Publisher

TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-014-0486-z

Keywords

two-dimensional; hexagonal boron nitride (h-BN); thermal conductivity; Raman spectroscopy

Funding

  1. Singapore National Research Foundation under NRF RF Award [NRF-RF2010-07]
  2. AFOSR MURI [FA9550-12-1-0035]
  3. Air Force Office of Scientific Research [FA9550-09-1-0581]
  4. U.S. Army Research Office MURI grant [W911NF-11-1-0362]
  5. U.S. Office of Naval Research MURI grant [N000014-09-1-1066]

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The thermal conduction of suspended few-layer hexagonal boron nitride (h-BN) sheets was experimentally investigated using a noncontact micro-Raman spectroscopy method. The first-order temperature coefficients for monolayer (1L), bilayer (2L) and nine-layer (9L) h-BN sheets were measured to be -(3.41 +/- 0.12) x 10(-2), -(3.15 +/- 0.14) x 10(-2) and -(3.78 +/- 0.16) x 10(-2) cm(-1)center dot K-1, respectively. The room-temperature thermal conductivity of few-layer h-BN sheets was found to be in the range from 227 to 280 W center dot m(-1)center dot K-1, which is comparable to that of bulk h-BN, indicating their potential use as important components to solve heat dissipation problems in thermal management configurations.

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