Journal
NANO RESEARCH
Volume 6, Issue 3, Pages 167-173Publisher
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-013-0292-z
Keywords
Co3O4; alpha-Fe2O3; nanowire; branched; lithium-ion battery; Nyquist plot
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Funding
- National Key Basic Research Program of China [2013CB934104]
- National Natural Science Foundation of China (NSFC) [21071033]
- Program for New Century Excellent Talents in University [NCET-10-0357]
- Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning
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We report a facile, two-step hydrothermal synthesis of a novel Co3O4/alpha-Fe2O3 branched nanowire heterostructure, which can serve as a good candidate for lithium-ion battery anodes with high Li+ storage capacity and stability. The single-crystalline, primary Co3O4 nanowire trunk arrays directly grown on Ti substrates allow for efficient electrical and ionic transport. The secondary alpha-Fe2O3 branches provide enhanced surface area and high theoretical Li+ storage capacity, and can also serve as volume spacers between neighboring Co3O4 NW arrays to maintain electrolyte penetration as well as reduce the aggregation during Li+ intercalation, thus leading to improved electrochemical energy storage performance.
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