Journal
NANO RESEARCH
Volume 4, Issue 12, Pages 1233-1241Publisher
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-011-0174-1
Keywords
Triple-layered; core-shell nanoparticles; heterogeneous catalysis; ammonia borane; hydrogen generation
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Funding
- National Institute of Advanced Industrial Science and Technology (AIST)
- Kobe University
- Japan Science and Technology Agency (JST)
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Magnetically recyclable Au/Co/Fe core-shell nanoparticles (NPs) have been successfully synthesized via a one-step in situ procedure. Transmission electron microscope (TEM), energy dispersive X-ray spectroscopic (EDS), and electron energy-loss spectroscopic (EELS) measurements revealed that the trimetallic Au/Co/Fe NPs have a triple-layered core-shell structure composed of a Au core, a Co-rich inter-layer, and a Fe-rich shell. The Au/Co/Fe core-shell NPs exhibit much higher catalytic activities for hydrolytic dehydrogenation of ammonia borane (NH(3)BH(3), AB) than the monometallic (Au, Co, Fe) or bimetallic (AuCo, AuFe, CoFe) counterparts.
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