Journal
NANO RESEARCH
Volume 3, Issue 1, Pages 1-7Publisher
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-010-1001-9
Keywords
CoO; LiCoO2; nanocrystals; lithium-ion batteries
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Funding
- National Natural Science Foundation of China (NSFC) [90606006]
- State Key Project of Fundamental Research for Nanoscience and Nanotechnology [2006CB932300]
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Shape control of nanocrystals has become a significant subject in materials science. In this work, we describe a convenient way to achieve morphology-controllable synthesis of CoO nanocrystals including octahedrons and spheres as well as LiCoO2 polyhedrons and spheres. In particular, we explain the formation of CoO octahedrons exposing only high-energy (111) facets using theoretical calculations; these should also be a useful tool for directing future face-controlled preparation of other nanocrystals. More importantly, the as-obtained LiCoO2 nanocrystals showed different electrochemical performance depending on their morphology, indicating that Li-insertion/deintercalation dynamics might be crystal face-sensitive.
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