Journal
NANO LETTERS
Volume 14, Issue 4, Pages 2033-2038Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl5001967
Keywords
P3HT; polymer crystal; cryo; electron microscopy; nanowire; organic solvent
Categories
Funding
- Dutch Polymer Institute (DPI) [682]
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Poly(3-hexylthiophene) (P3HT) assemblies in vitrified organic solvents were visualized at nanometer scale resolution by cryo-transmission electron microscopy, low dose electron diffraction, and cryo-tomography revealing a three-dimensional lamellar structure formed by the stacking of the conjugated backbones of P3HT with a distance of 1.7 nm and increased order in the bulk of the nanowire. This combination of techniques reveals local structures in dispersion and the condensed state that play a crucial role in the performance of organic electronic devices.
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