High Responsivity Photoconductors Based on Iron Pyrite Nanowires Using Sulfurization of Anodized Iron Oxide Nanotubes

Iron pyrite (FeS2) nanostructures are of considerable interest for photovolatic applicaitons due to improved material quality compared to their bulk counterpart. As an abundant and nontoxic semiconductor, FeS2 nanomaterials offer great opportunities for low-cost and green photovoltaic technology. This paper describes the fabrication of FeS2 nanowire arrays via sulfurization of iron oxide nanotubes at relatively low temperatures. A facile synthesis of ordered iron oxide nanotubes was achieved throught anodization of iron foils. Characterization of the iron sufide nanowires indicates that pyrite structures were formed. A prototype FeS2 nanowire photoconductor demonstrates very high responsivity (>3.0 A/W). The presented method can be further explored to fabricate various FeS2 nanostructures, such as nanoparticles, nanoflowers, and nanoplates.