Journal
NANO LETTERS
Volume 13, Issue 3, Pages 1153-1161Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl304569d
Keywords
van der Waals epitaxy; nanowire; MOCVD; InGaAs; InAs; phase segregation; phase separation; graphene
Categories
Funding
- DOE through the Frederick Seitz Materials Research Laboratory [DEFG02-07ER46471]
- National Science Foundation DMR [1006581]
- Air Force Office of Scientific Research (AFOSR) [FA9550-10-1-0082]
- Army Research Office (ARO) through the National Defense Science and Engineering Graduate Fellowship
- Beckman Foundation
- National Science Foundation (NSF) [CHE 10-38015]
- Office of Naval Research (ONR) [N00014-10-1-0853]
- U.S. Department of Energy [DE-FG02-07ER46453, DE-FG02-07ER46471]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1038015] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1006581] Funding Source: National Science Foundation
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The growth of high-density arrays of vertically oriented, single crystalline In As NWs on graphene surfaces are realized through the van der Waals (vdW) epitaxy mechanism by metalorganic chemical vapor deposition (MOCVD). However, the growth of In GaAs NWs on graphene results in spontaneous phase separation starting from the beginning of growth, yielding a well-defined InAs-InxGa1-xAs (0.2 < x < 1) core-shell structure. The core-shell structure then terminates abruptly after about 2 mu m in height, and axial growth of uniform composition InxGa1-xAs takes place without a change in the NW diameter. The InxGa1-xAs shell composition changes as a function of indium flow, but the core and shell thicknesses and the onset of nonsegregated InxGa1-xAs axial segment are independent of indium composition. In contrast, no In GaAs phase segregation has been observed when growing on MoS2, another two-dimensional (2D) layered material, or via the Au-assisted vapor-liquid-solid (VLS) mechanism on graphene. This spontaneous phase segregation phenomenon is elucidated as a special case of van der Waals epitaxy on 2D sheets. Considering the near lattice matched registry between InAs and graphene, InGaAs is forced to self-organize into InAs core and InGaAs shell segments since the lack of dangling bonds on graphene does not allow strain sharing through elastic deformation between InGaAs and graphene.
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