4.8 Article

Hybrid Energy Cell for Degradation of Methyl Orange by Self-Powered Electrocatalytic Oxidation

Journal

NANO LETTERS
Volume 13, Issue 2, Pages 803-808

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl3046188

Keywords

Hybrid energy cell; triboelectric nanogenerator; pyroelectric nanogenerator; self-powered; methyl orange; electrodegradation

Funding

  1. Airforce, MURI
  2. U.S. Department of Energy, Office of Basic Energy Sciences [DE-FG02-07ER46394]
  3. NSF [CMMI 0403671]
  4. Knowledge Innovation Program of the Chinese Academy of Sciences [KJCX2-YW-M13]
  5. National Research Foundation of Korea (NRF)
  6. Ministry of Education, Science, and Technology (MEST) [2011-0018645]

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In general, methyl orange (MO) can be degraded by an electrocatalytic oxidation process driven by a power source due to the generation of superoxidative hydroxyl radical on the anode. Here, we report a hybrid energy cell that is used for a self-powered electrocatalytic process for the degradation of MO without using an external power source. The hybrid energy cell can simultaneously or individually harvest mechanical and thermal energies. The mechanical energy was harvested by the triboelectric nanogenerator (TENG) fabricated at the top by using a flexible polydimethysiloxane (PDMS) nanowire array with diameters of about 200 nm. A pyroelectric nanogenerator (PENG) was fabricated below the TENG to harvest thermal energy. The power output of the device can be directly used for electrodegradation of MO, demonstrating a self-powered electrocatalytic oxidation process.

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