4.8 Article

Nanoscale Magnetism Control via Surface and Exchange Anisotropy for Optimized Ferrimagnetic Hysteresis

Journal

NANO LETTERS
Volume 12, Issue 7, Pages 3716-3721

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl301499u

Keywords

Magnetism; magnetic anisotropy; exchange coupling core-shell structure; cube nanoparticle; hypertherrnia

Funding

  1. Creative Research Initiative [2010-0018286]
  2. WCU [R32-10217]
  3. BK21 for chemistry and medical science
  4. NRF of Korea [2011-0017611]
  5. Mid-Career Researcher Program [2009-0081001]
  6. Hi Seoul Science/Humanities Fellowship

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With the aim of controlling nanoscale magnetism, we demonstrate an approach encompassing concepts of surface and exchange anisotropy while reflecting size, shape, and structural hybridization of nanoparticles. We visualize that cube has higher magnetization value than sphere with highest coercivity at 60 nm. Its hybridization into core-shell (CS) structure brings about a 14-fold increase in the coercivity with an exceptional energy conversion of magnetic field into thermal energy of 10600 W/g, the largest reported to date. Such capability of the CS-cube is highly effective for drug resistant cancer cell treatment.

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