Journal
NANO LETTERS
Volume 12, Issue 4, Pages 1784-1788Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl203649p
Keywords
Molybdenum oxide; anode; lithium ion battery; hybrid architecture; silicon
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Funding
- US Department of Energy [DE-FG02-05ER64071, DE-FG02-07ER46375]
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In this study, vertical nanowire arrays of MoO3-x grown on metallic substrates with diameters of similar to 90 nm show high-capacity retention of similar to 630 mAhg(-1) for up to 20 cycles at 50 mAg(-1) current density. Particularly, they exhibit a capacity retention of similar to 500 mAhg(-1) in the voltage window of 0.7-0.1 V, much higher than the theoretical capacity of graphite. In addition, 10 nm Si-coated MoO3-x nanowire arrays have shown a capacity retention of similar to 780 mAhg(-1), indicating that hybrid materials are the next generation materials for lithium ion batteries.
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