Journal
NANO LETTERS
Volume 12, Issue 9, Pages 4455-4459Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl301232t
Keywords
Bilayer graphene; TEM; strain; constriction; lattice expansion
Categories
Funding
- DFG [RU1540/8-1]
- Agencia de Gestio d'Ajuts Universitaris i de Recerca de la Generalitat de Catalunya [2010_BP_A_00301]
- Dutch Foundation for Fundamental Research on Matter
- EU
- Freistaat Sachsen
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Our understanding of sp(2) carbon nanostructures is still emerging and is important for the development of high performance all carbon devices. For example, in terms of the structural behavior of graphene or bilayer graphene at high bias, little to nothing is known. To this end, we investigated bilayer graphene constrictions with closed edges (seamless) at high bias using in situ atomic resolution transmission electron microscopy. We directly observe a highly localized anomalously large lattice expansion inside the constriction. Both the current density and lattice expansion increase as the bilayer graphene constriction narrows. As the constriction width decreases below 10 nm, shortly before failure, the current density rises to 4 x 10(9) A cm(-2) and the constriction exhibits a lattice expansion with a uniaxial component showing an expansion approaching 5% and an isotropic component showing an expansion exceeding 1%. The origin of the lattice expansion is hard to fully ascribe to thermal expansion. Impact ionization is a process in which charge carriers transfer from bonding states to antibonding states, thus weakening bonds. The altered character of C-C bonds by impact ionization could explain the anomalously large lattice expansion we observe in seamless bilayer graphene constrictions. Moreover, impact ionization might also contribute to the observed anisotropy in the lattice expansion, although strain is probably the predominant factor.
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