4.8 Article

Longitudinal Splitting of Boron Nitride Nanotubes for the Facile Synthesis of High Quality Boron Nitride Nanoribbons

Journal

NANO LETTERS
Volume 11, Issue 8, Pages 3221-3226

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl2014857

Keywords

Boron nitride; nanomaterials; nanoribbons; splitting; nanotubes

Funding

  1. Office of Science, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, of the U.S. Department of Energy [DE-AC02-05CH11231]
  2. Center of Integrated Nanomechanical Systems (COINS) with NSF [EEC-0425914]
  3. Office of Naval Research MURI
  4. Air Force Research Laboratory through University Technology Corporation [09-S568-064-01-C1]
  5. Air Force Office of Scientific Research [FA9550-09-1-0581]

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Boron nitride nanoribbons (BNNRs), the boron nitride structural equivalent of graphene nanoribbons (GNRs), are predicted to possess unique electronic and magnetic properties. We report the synthesis of BNNRs through the potassium-intercalation-induced longitudinal splitting of boron nitride nanotubes (BNNTs). This facile, scalable synthesis results in narrow (down to 20 nm), few sheet (typically 2-10), high crystallinity BNNRs with very uniform widths. The BNNRs are at least 1 mu m in length with minimal defects within the ribbon plane and along the ribbon edges.

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