4.8 Article

Approaching the Theoretical Elastic Strain Limit in Copper Nanowires

Journal

NANO LETTERS
Volume 11, Issue 8, Pages 3151-3155

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl201233u

Keywords

Theoretical elastic limit; size dependence; copper nanowire; in situ TEM

Funding

  1. C-NSF [50831001]
  2. National Outstanding Young Scientist Grant of China [10825419]
  3. National 973 Program of China [2009CB623700]
  4. JHU [US-NSF-DMR-0904188]

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Three sets of uniaxial tensile tests have been performed in situ in transmission electron microscopy/high-resolution electron microscopy on Cu nanowires (NWs) to accurately map out the sample size dependence of elastic strain limit. Atomic-resolution evidence was obtained for an exceedingly large recoverable strain (as much as 7.2%) that can be sustained in the lattice of a single-crystalline Cu NW with a diameter of similar to 5.8 nm. This ultrahigh elastic strain is consistent with the predictions from molecular dynamics simulations for nanowires and approaches the ideal elastic limit predicted for Cu by ab initio calculations.

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