4.8 Article

Batteries for Efficient Energy Extraction from a Water Salinity Difference

Journal

NANO LETTERS
Volume 11, Issue 4, Pages 1810-1813

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl200500s

Keywords

Salinity-gradient power; mixing entropy; sodium intercalation; energy harvesting

Funding

  1. King Abdullah University of Science and Technology (KAUST) [KUS-11-001-12, KUS-I1-003-13]
  2. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering through the SLAC National Accelerator Laboratory [DE-AC02-76SF0051]

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The salinity difference between seawater and river water is a renewable source of enormous entropic energy, but extracting it efficiently as a form of useful energy remains a challenge. Here we demonstrate a device called mixing entropy battery, which can extract and store it as useful electrochemical energy. The battery, containing a Na2-xMn5O10 nanorod electrode, was shown to extract energy from real seawater and river water and can be applied to a variety of salt waters. We demonstrated energy extraction efficiencies of up to 74%. Considering the flow rate of river water into oceans as the limiting factor, the renewable energy production could potentially reach 2 TW, or similar to 13% of the current world energy consumption. The mixing entropy battery is simple to fabricate and could contribute significantly to renewable energy in the future.

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