Journal
NANO LETTERS
Volume 10, Issue 11, Pages 4664-4667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl102880k
Keywords
Thermoelectrics; nanocomposites; conducting polymer; nanocrystals; solution process
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Funding
- Department of Energy BES-LBL
- Office of Science, Office of Basic Energy Sciences, Scientific User Facilities Division, of the U.S. Department of Energy [DE-AC02-05CH11231s]
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We report the synthesis and thermoelectric characterization of composite nanocrystals composed of a tellurium core functionalized with the conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). Solution processed nanocrystal films electronically out perform both PEDOT:PSS and unfunctionalized Te nanorods while retaining a polymeric thermal conductivity, resulting in a room temperature ZT similar to 0.1. This combination of electronic and thermal transport indicates the potential for tailored transport in nanoscale organic/inorganic heterostructures.
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