4.8 Article

Nanoporous Au-Pt Alloys As Large Strain Electrochemical Actuators

Journal

NANO LETTERS
Volume 10, Issue 1, Pages 187-194

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl903262b

Keywords

Nanoporous metals; actuation; surface stress; gold; platinum

Funding

  1. Deutsche Forschungsgemeinschaft
  2. Alexander Von Humboldt Foundation

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Nanoporous Au-Pt alloys with pore- and ligament size down to few nanometers were fabricated by dealloying Ag-Au-Pt. Owing to the small structure size and large specific Surface area, the surface stress and its variation give rise to significant stress and strain in the bulk of these materials. In fact, dilatometry experiments find electrochemical actuation with large reversible strain amplitude. The linear strain reaches similar to 1.3% and strain energy density is up to 6.0 MJ/m(3). The associated stresses may approach the elastic limit of the alloy.

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