Journal
NANO LETTERS
Volume 10, Issue 10, Pages 4055-4060Publisher
AMER CHEMICAL SOC
DOI: 10.1021/nl102109s
Keywords
Electron-hole separation; nanowire superlattice; type II-type I transition
Categories
Funding
- U S Department of Energy. Office of Basic Energy Science, Division of Materials Sciences and Engineering [DE-AC36-08G028308]
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Nanowire-superlattices with different structural phases along the nanowire direction, such as wurtzite (WZ) and zincblende (ZB) forms of the same compound, often exhibit a type II band-alignment with electrons on ZB and holes on WZ This is a material property of most of III V semiconductors We show via InP nanowires that as the nanowire diameter decreases, quantum-confinement alters this basic material property, placing both electrons and holes on the same (ZB) phase This structural design causes a dramatic increase in absorption strength and reduced radiative lifetime
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