4.8 Article

Quantum Dot/J-Aggregate Blended Films for Light Harvesting and Energy Transfer

Journal

NANO LETTERS
Volume 10, Issue 10, Pages 3995-3999

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl1018639

Keywords

Quantum dot; J-aggregate; energy transfer; electrostatic; thin film

Funding

  1. National Science Foundation
  2. DOE Basic Energy Sciences [DE-FG02-07ER46454]
  3. Chesonis Family Foundation
  4. ISN [W911NF-07-D-0004]
  5. NSF-MRSEC [DMR-0819762]
  6. U.S. Department of Energy (DOE) [DE-FG02-07ER46454] Funding Source: U.S. Department of Energy (DOE)
  7. Division Of Materials Research
  8. Direct For Mathematical & Physical Scien [0819762, GRANTS:13714308] Funding Source: National Science Foundation

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This paper describes the solution preparation of thin films composed of quantum dots and thiacyanine J-aggregates, making use of the size tunable emission of quantum dots and the narrow, intense absorption off-aggregates in the solid state These blended films exhibit 90% energy transfer efficiency from J-aggregates to quantum dots and can uniformly cover a large area Because the presence of chef-aggregates enhances the QD photoluminescence intensity by 2 5-fold over QDs alone, these solid state materials may be useful in downconversion applications or in fundamental investigations of light harvesting

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